8 |
Study of Compounds |
A. Hydrogen Chloride
preparation of hydrogen
chloride from sodium chloride; refer to the
density and solubility of hydrogen chloride
(fountain experiment); reaction with
ammonia; acidic properties of its solution. |
- The laboratory method of preparation can be learnt in terms of reactants, product, condition, equation, diagram or setting of the apparatus, procedure, observation, precaution, collection of the gas and identification .
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• Simple experiment to show the density of the gas (Hydrogen Chloride) –heavier than air. |
• Solubility of hydrogen chloride (fountain experiment); setting of the apparatus, procedure, observation, inference. |
- Method of preparation of hydrochloric acid by dissolving the gas in water- the special funnel arrangement and the mechanism by which the back suction is avoided should be learnt.
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- Acidic properties of its solution – reaction with metals, their oxides, hydroxides and carbonates to give their chlorides; decomposition of carbonates, hydrogen carbonates, sulphides, sulphites.
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- Precipitation reactions with silver nitrate solution and lead nitrate solution.
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B. Ammonia : its laboratory preparation from
ammonium chloride and collection; ammonia
from nitrides like Mg3N2 and AlN and
ammonium salts. Manufacture by Haber’s
Process; density and solubility of ammonia
(fountain experiment); aqueous solution of
ammonia; its reactions with hydrogen chloride
and with hot copper (II) oxide and chlorine;
the burning of ammonia in oxygen; uses of
ammonia. |
- Laboratory preparation from ammonium chloride and collection; (the preparation to be studied in terms of, setting of the apparatus and diagram, procedure, observation, collection and identification.
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- Ammonia from nitrides like Mg3N2 and AlN using warm water.
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Ammonia from ammonium salts using alkalies. |
The reactions to be studied in terms of reactants, products, conditions and
equations. |
Manufacture by Haber’s Process. |
Density and solubility of ammonia (fountain experiment). |
- The burning of ammonia in oxygen.
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- The catalytic oxidation of ammonia (with conditions and reaction)
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- Its reactions with hydrogen chloride and with hot copper (II) oxide, lead monoxide and chlorine (both chlorine in excess and ammonia in excess).
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All these reactions may be studied in terms ofreactants, products, conditions, equations and observations. |
- Aqueous solution of ammonia – reaction with sulphuric acid, nitric acid, hydrochloric acid and solutions of iron(III) chloride, iron(II) sulphate, lead nitrate, zinc nitrate and copper sulphate.
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Uses of ammonia – manufacture of fertilizers, explosives, nitric acid, refrigerant gas (Chlorofluro carbon – and its suitable alternatives which are nonozone depleting), and cleansing agents. |